Enantioselective α- and γ-Alkylation of α,β-Unsaturated Aldehydes Using Dienamine Activation
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The enantioselective alkylation of α,β-unsaturated aldehydes with stabilized carbocations as electrophiles via the activation as dienamine intermediates is described. This unique application of dienamine catalysis allows for the first enantioselective γ-alkylation of linear α,β-unsubstituted enals.
创建时间：
2016-02-24
