Organocatalytic Asymmetric Synthesis of Bridged Tetrahydrobenzo[<i>b</i>]azepines/oxepines
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The asymmetric synthesis of bridged tetrahydrobenzo[b]azepine and oxepine derivatives through chiral Brønsted acid catalyzed asymmetric aza-Piancatelli rearrangement/Michael addition sequence has been developed. The reaction proceeds under mild reaction conditions to afford the final bridged cyclic products in good yields with excellent enantio- and diastereoselectivities.
创建时间：
2022-09-28
