Exploring Synthetic Routes to Heteroleptic UIII, UIV and ThIV Bulky Bis(silyl)amide Complexes
收藏官方服务:
资源简介:
Research support data for paper.
学术论文研究支撑数据
应用场景:
创建时间:
2018-02-25
相关数据集
Isolation of Uranyl Dicyanamide Complexes from N‑Donor Ionic Liquids
An ionic liquid (IL) approach for soft-donor f-element chemistry has been demonstrated by the isolation of several new uranyl dicyanamide complexes through reactions of UO2(NO3)2·6H2O with dicyanamide
NIAID Data Ecosystem80
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex
Reduction of IU(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U(II) complex, U(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectrosco
NIAID Data Ecosystem50
Polymeric Structure of Oxalato-Bridged Complexes of Tetravalent Actinides Th, U, Np and Pu
A series of isostructural oxalates of Th, U, Np, and Pu have been synthesized. The crystal structure of {C(NH2)3}4[An(C2O4)4]·2H2O comprises infinite [An(C2O4)4]4n− chains, guanidinium cations and
NIAID Data Ecosystem30
The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine
The reaction between Ph3PO dissolved in acetone and “PuO2Cl2” in dilute HCl resulted in the formation of [PuO2Cl2(Ph3PO)2]. Crystallographic characterization of the acetone solvate revealed the expect
NIAID Data Ecosystem60
Preference for Nitrogen versus Oxygen Donor Coordination in Uranyl- and Neptunyl(VI) Complexes
The first actinyl phosphinimine complexes have been synthesized and, in the case of uranium, exhibit strong U−N interactions. Competition reactions clearly demonstrate a surprising preference for R3P
NIAID Data Ecosystem40



