Competition between sp3‑C–N vs sp3‑C–F Reductive Elimination from PdIV Complexes
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This communication describes the design of a model system that allows direct investigation of competing sp3-C–N and sp3-C–F bond-forming reductive elimination from a PdIV fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.
创建时间：
2016-02-17
