Nickel-Catalyzed Isomerization of 2-Methyl-3-butenenitrile<sup>†</sup>
收藏NIAID Data Ecosystem2026-03-06 收录
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The isomerization of the branched 2M3BN to the linear 3PN by a DPEphosNi species has been investigated by means of variable-temperature NMR spectroscopy, and activation parameters have been determined. An intermediate in this reaction, which is formed via C−C bond activation, could be trapped by addition of ZnCl2, and the molecular structure of the corresponding Ni(II) complex has been determined by X-ray crystallography.
创建时间：
2016-05-06
