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Π-Rich σ2P-Ligands: Unusual Coordination Behavior of 1H-1,3-Benzazaphospholes Toward Late Transition Metals

NIAID Data Ecosystem2026-03-08 收录

有机金属化学

配体设计

数据链接：

https://figshare.com/articles/dataset/_Rich_sup_2_sup_P_Ligands_Unusual_Coordination_Behavior_of_i_1H_i_1_3_Benzazaphospholes_Toward_Late_Transition_Metals/1263558 数据链接链接失效反馈

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GRAPHICAL ABSTRACT

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创建时间：

2015-07-01

不对称催化

配体设计

Enantioselective catalysis in moderate to excellent yields and ee’s has been accomplished using a phosphaalkene-based ligand system. Specifically, the palladium-catalyzed allylic alkylation of 1,3-dip

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Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters †

金属簇合物合成

有机金属化学

The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradi

NIAID Data Ecosystem90

Preparation of LGe(Se)OH: A Germanium Analogue of a Selenocarboxylic Acid (L = HC[(CMe)(NAr)] 2 , Ar = 2,6- i Pr 2 C 6 H 3 )

有机金属化学

锗硒配合物表征

LGe(Se)OH (2) (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) was obtained by oxidative addition of red selenium to LGeOH (1). Compound 2 was characterized by IR, multinuclear NMR, EI-MS, and single-crystal

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Structure and Reactivity of Chromium(VI) Alkylidenes

有机金属化学

铬配合物合成

Bis(arylimido)Cr(VI) dialkyls lacking β-hydrogen decompose by α-hydrogen abstraction and, upon trapping with triphenylphosphine, yield isolable alkylidene complexes. Two such complexes, namely (ArN

NIAID Data Ecosystem100

Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]

有机金属化学

化合物稳定性

The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn

NIAID Data Ecosystem70

Π-Rich σ<sup>2</sup>P-Ligands: Unusual Coordination Behavior of <i>1H</i>-1,3-Benzazaphospholes Toward Late Transition Metals

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