Silver(I)–Ferrophox Catalyzed Enantioselective Desymmetrization of Cyclopentenedione: Synthesis of Highly Substituted Bicyclic Pyrrolidines
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A highly enantioselective desymmetrization of prochiral cyclopentene-1,3-dione via [3 + 2] cycloaddition of azomethine ylide using a silver(I)–ferrophox complex has been demonstrated. The method has been utilized in the synthesis of highly functionalized enantioenriched 5,5-fused bicyclic pyrrolidine derivatives under mild reaction conditions.
创建时间：
2016-02-12
