Kinetic Resolution of Hindered Morita–Baylis–Hillman Adducts by Rh(I)-Catalyzed Asymmetric 1,4-Addition/β-Hydroxyelimination
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A kinetic resolution of hindered Morita–Baylis–Hillman adducts has been successfully achieved in excellent selectivities via Rh(I)-catalyzed asymmetric 1,4-addition/β-hydroxyelimination with the use of a chiral sulfinamide/olefin hybrid ligand. This study provides a novel and efficient access to both optically active hindered highly functionalized alkenes and Morita–Baylis–Hillman adducts.
创建时间：
2011-09-16
