Preparation of Bicyclo[3.2.0]heptane-2-<i>e</i><i>ndo</i>,7-<i>e</i><i>ndo</i>-diols: 1,3-Diols with a Chiral Rigid Backbone<sup>†</sup>
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The easily available bicyclo[3.2.0]hept-3-en-6-ones (1a−f) have been converted into the corresponding bicyclo[3.2.0]heptane-2-endo,7-endo-diols (4a−f) in an efficient and stereoselective fashion. This preparation opens a route to a family of 1,3-diols with a chiral rigid backbone, potentially suitable as nonracemic precursors for bidentate ligands in asymmetric synthesis.
创建时间：
2004-02-20
