Synthesis of Chiral α‑Amino Tertiary Boronic Esters by Enantioselective Hydroboration of α‑Arylenamides
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The rhodium-catalyzed asymmetric hydroboration of α-arylenamides with BI-DIME as the chiral ligand and (Bpin)2 as the reagent yields for the first time a series of α-amino tertiary boronic esters in good yields and excellent enantioselectivities (up to 99% ee).
创建时间：
2015-06-03
