Highly Efficient Chemical Kinetic Resolution of Bishomoallylic Alcohols: Synthesis of (<i>R</i>)-Sulcatol
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A highly efficient chemical kinetic resolution of bishomoallylic alcohols was developed when the alcohols underwent In(OTf)3-catalyzed 3,5-oxonium-ene-type cyclization with steroidal aldehyde 2. Consistently high enantiomeric excess (up to >99%) was obtained.
创建时间：
2004-09-16
