Chiral P,N,N-Ligands for the Manganese-Catalyzed Asymmetric Formal Hydroamination of Allylic Alcohols
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Application of chiral P,N,N-ligands in the manganese-catalyzed formal asymmetric hydroamination of allylic alcohols through a borrowing-hydrogen strategy was demonstrated. A series of racemic allylic alcohols could react with various secondary amines, affording chiral γ-amino alcohols in up to 93% yield with 96% ee.
创建时间：
2025-08-07
